Synthesis of Zn and CNTs based SSZ 13 cha type zeolite catalyst for ammonia selective catalytic reduction of nox
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Abstract
Due to the sheer rising cost of crude oil and the intense emphasis on
newlinefuel economy, vehicle manufacturers are focusing on various lean burn and
newlinediesel engines. The rapid adoption of diesel engines in the automobile
newlineindustry has resulted in an increase in global NOX emissions, one of the major
newlinepollutants. It is also one of the secondary greenhouse gases, forming groundlevel
newlineozone and photochemical smog when it reacts with other atmospheric
newlinegases. Furthermore, NOX emissions cause acid rain by reacting with water and
newlineoxygen in the atmosphere. NOX emissions from both on-road and off-road
newlinevehicles are becoming increasingly stricter, according to the most recent
newlineEuropean and American emission standards, and thus must be addressed
newlineimmediately. Selective catalytic reduction has been the most widely used
newlineexhaust gas after-treatment technique to reduce NOX emissions from diesel
newlineexhaust for the past three decades. The basic principle behind this technique is
newlineto use ammonia or urea as a reductant to convert harmful NOX emissions into
newlineN2 and H2O.To date, zeolite-based composite is widely used catalyst in SCR to its excellent activity of NOX at higher temperatures with wide operating range of
newlinetemperature window, tolerance towards sulfur and reasonable cost of
newlineproduction
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