Stimuli Responsive Ionic Liquid Based Low Molecular Weight Gelators for Biological and Environmental Applications
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Abstract
liquids (ILs) have been at the cutting edge of the most promising science in
newlinerecent times due to its technological brilliance and unique properties, which put them
newlineabove the rest of the compounds. They are commonly defined as a class of salts
newlinecomposed of discrete cations and anions with a oC. They are pertinent
newlineadvanced materials with unprecedented physicochemical properties such as negligible
newlinevapor pressure, wide liquid range, excellent thermal stability, wide electrochemical
newlinepotential window, superb solubility for a wide range of organic, inorganic,
newlineorganometallic, and biological substances. These properties address the growing needs of
newlinethem in several resources as well as in various industries not limited to energy,
newlinepharmaceuticals, and process chemicals to cite a few. Among all of these properties, their
newlineability to fine-tune their properties through merely changing the constituting cations
newlineand/or anions are the most promising as they allow the material scientists and
newlinetechnologists to tailor-made the structures and so their applications. The tunability of ILs
newlineallows for functional diversity leading to compounds with a myriad of functional
newlinecapabilities including hydrophilic to hydrophobic, electrolytic to amphiphilic, toxic to
newlinenon-toxic, biodegradable to non-biodegradable, highly viscous to lowest viscous, highly
newlinethermally stable to thermally unstable, non-polar to highly polar and functionalized to
newlinenon-functionalized. These ILs are also called as Task-Specific or tailor-made ILs. The
newlineaddition of an ion-tethered functional group onto IL structures has generated a new
newlinesubclass of ILs, known as functionalized ILs.
newlineStimuli-responsive functionalized ionic liquids that have wide applications in the
newlinebiological and environmental field. Various properties are to be tailored based on the size
newlineand shape of the aggregates. Aggregate structures such as spherical micelles, cylinder
newlinemicelles, vesicle, and hydrogels are formed by ILBSs in aqueous solution are widely used
newlineinsolubilizing and emulsifying agents, detergent,